Morphological and Raman Study of an Anodized Tio2 Nanotubular Matrix without Presence of Nanograss, Using Graphite as Cathode

Abstract

Marcos Luna Cervantes, Adriana Baez Rodríguez, Julian Hernandez Torres and Luis Zamora Peredo

One set of TiO2 nanotubes is anodized to identify and study the time lapse of a matrix of them without presence of nanograss as a residual layer. The anodization process consists of an organic media of ethylene glycol and NH4 F salts, constant voltage for a time period from 10 to 60 minutes. All anodized samples are rinsed and annealed to 400 °C by 2 hours to obtain an anatase crystalline structure. The morphological characterization was carried out by Field Emission Scanning Electron Microscopy to verify the presence of the nanotubes and calculate the surface roughness factor and film porosity. It was observed that roughness factor and porosity doesn’t have important variations, as time function, except for 60 minutes where nanograss has a strong presence and the gaps between nanotubes are minimal. Raman Spectroscopy was used for optical characterization in order to identify the changes in signal intensity and Eg mode Shift associated with anodization time. It was observed that intensity suffers an increment and Eg mode Shift suffers a decrement as thickness function (anodization time)

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